The Basics
Perchlorate
What is perchlorate?
- Perchlorate salts are colorless solids that readily dissolve in water. They are used in the production of flares, dyes, and paints. In addition, they occur naturally and are found in some imported fertilizers and household bleach.
What are the common uses of perchlorate?
- Perchlorate is used in the production of fireworks, road flares, explosives, matches, and automotive air bags in addition to a number of military uses.
Why is perchlorate on the DoD Emerging Contaminants Action List?
- Perchlorate has a number of critical DoD applications in missiles, rockets, and munitions. While DoD is working to reduce the use of perchlorate, some of DoD’s uses result in releases to the environment.
- The National Academy of Sciences found that exposure to perchlorate may adversely affect the thyroid function of pregnant women, fetuses, and infants.
- Perchlorate has been found in over 35 states prompting EPA and some states to take measures to address potential public health concerns.
- Federal and state agencies continue to investigate sources and exposure routes for perchlorate; new evidence suggests that food, rather than drinking water, may be a significant source of exposure. The science regarding naturally-occurring and man-made perchlorate sources, exposure routes, toxicity, and ultimate environmental fate continues to evolve.
- Perchlorate is by far the safest, most efficient, and stable propellant oxidizer available to federal agencies. Its stability and reliability are crucial for its safe storage, handling, and performance, ensuring force protection, safety, and military readiness.
- In missile and rocket motors, perchlorate is embedded in a solid material that does not readily dissolve in water.
How is DoD managing the risk posed by perchlorate?
- DoD is addressing perchlorate releases at installations and Formerly Used Defense Sites as part of its overall environmental restoration program. Response actions are taken, if necessary, as indicated by site-specific risk assessments performed in coordination with federal and state regulators.
- Groundwater that is used for drinking is treated to remove perchlorate at the few DoD sites where it is found to pose a potential threat to public health.
- DoD has a policy to sample for perchlorate at existing installations and Formerly Used Defense Sites in accordance with federal and state regulations. DoD has collected over 45,000 samples nationwide and, for the vast majority of sites, laboratory tests have not detected perchlorate in drinking water, groundwater, or soils at levels that pose risks to public health.
- Recent surveys of DoD installations in California and Massachusetts have generally found levels well below EPA health-based guidelines.
- EPA, other government agencies, water suppliers, and industry are also actively testing for the presence of perchlorate in drinking water, surface water, groundwater, soil, and food supplies.
- DoD has spent over $114M on research regarding perchlorate treatment, substitutes, and detection methodologies.
- DoD recently began using more environmentally-friendly substitute materials in training flares and munitions on Army training ranges. They account for an average of about 70% of the perchlorate used on ranges.
Where can I get more information?
- The Agency for Toxic Substances and Disease Registry has health risk information available here: http://www.atsdr.cdc.gov/toxfaqs/tf.asp?id=893&tid=181
- For additional information on DoD's work on the multiple sources of perchlorate, characterizing risks, and fielding substitutes for the compound, please click here
Multiple Sources of Perchlorate in the Environment (PDF)
This article details efforts to identify sources of the contaminant in the environment the majority of which appear to be from non-Defense related discharges.
DoD 2009 Overview of Perchlorate Information, Issues and Activities (PDF)
Findings from Perchlorate Sampling - Article from EM Journal (PDF)
Article co-authored by California Regulators and DoD personnel summarizes the process and findings of DoD-CA perchlorate prioritization effort and national efforts to find out if DoD a major contributor to perchlorate found in drinking water supplies.
EPA Health Advisory for Perchlorate - Jan 2009 (PDF)
EPA report on new Health Advisory Goal for perchlorate issued Jan 8, 2009
DoD Beehler (PDF)
DoD and GAO testimony on Department of Defense Activities Related to TCE, Perchlorate, and Other Emerging Contaminants, before the Subcommittee on Readiness, Committee on Armed Services, House of Representatives. 12 July 2007
EPA Perchlorate Policy 2006 (PDF)
EPA Perchlorate guidance. This guidance replaces previous Office of Solid Waste and Emergency Response (OSWER) guidance and the accompanying questions and answers (referenced below) regarding perchlorate under the National Contingency Plan, 40 CFR Part 300.
Mass DEP perchlorate- 310CMR22-07282006 (PDF)
Massachusetts was the first state in the nation to promulgate drinking water and waste site cleanup standards for the chemical perchlorate, setting the standard at 2 parts per billion (ppb).
Mass DEP Promulgates Perchlorate Standards (PDF)
Massachusetts was the first state in the nation to promulgate drinking water and waste site cleanup standards for the chemical perchlorate, setting the standard at 2 parts per billion (ppb).
August 2007 (PDF)
DoD Perchlorate Handbook Aug 2007
Rule (DOC)
The state of California has adopted an enforceable drinking water standards for perchlorate. The MCL of 6 ug/L will be effective October 18, 2007. The rule is at California Code of Regulations, Title 22, Chapter 15.
UPDATED INFORMATIVE DIGEST (DOC)
New Calif State Drinking Water Standard for Perchlorate
Statement of Reason (DOC)
New Calif State Drinking Water Standard for Perchlorate
ATSDR Toxicological Profile for Perchlorates, September 2008 (PDF)
The Agency for Toxic Substances and Disease Registry (ATSDR) has released a final perchlorate toxicological profile. The 299 page profile discusses health effects public health risk of perchorate exposure. The profile includes a Minimal Risk Level for oral exposures with a chronic reference dose (RfD) of 0.0007 mg/kg/day for the chronic oral MRL for the perchlorate anion. This value is based on a 2005 National Academy of Sciences report and is the value that EPA has also adopted. The results from newer studies did not change ATSDRs bottom-line recommendation.
EPA 2008 Revised Assessment Guidance on Perchlorate (PDF)
EPA Jan 2009 guidance update on Assessment of Perchlorate.



